Corps de l’article

INTRODUCTION

The Creignish Hills and North Mountain areas of western Cape Breton Island (Fig. 1) consist mostly of Neoproterozoic metasedimentary and plutonic rocks typical of the Bras d’Or terrane of Barr and Raeside (1989) and Raeside and Barr (1990). These areas have been mapped and studied by numerous workers over the years (e.g., Kelly 1967; Milligan 1970; White et al. 1990; Campbell 1990; Justino 1991; Lynch and Brisson 1996; Keppie et al. 1998a; White et al. 2003; Wessel et al. 2005), and the resulting interpretations are varied, hampered by complex field relations and limited age constraints. White and Boehner (2008) compiled and evaluated existing data to produce a revised 1:50 000-scale geological map of the Whycocomagh NTS sheet, and Swanton et al. (2010) extended the mapping to the northeast to include metamorphic and plutonic rocks in the Lewis Mountain-Aberdeen Ridge area (Fig. 2).

The purpose of this paper is to provide an overview of the pre-Devonian geology based on these maps, and to present a new detrital zircon age spectrum from a metasedimentary unit in the Creignish Hills which better constrains the age of the metamorphic units in the area. We also take the opportunity to publish the full database for U-Pb zircon ages from the area reported only in preliminary form by White et al. (2003), and to present previously unpublished total fusion 40Ar/39Ar ages for muscovite from a metasedimentary unit in the Creignish Hills. In addition, we re-examine chemical data from Neoproterozoic plutons in these areas in the light of the current age information, and propose revised names for some of the rock units in the area based on all of the currently available data.

Figure 1

Figure 1. Simplified geological map of the Bras d’Or terrane of central Cape Breton Island after Raeside and Barr (1990) showing the location of the Creignish Hills and North Mountain areas and other areas mentioned in the text. Inset map shows the location of Cape Breton Island in the northern Appalachian orogen with tectonostratigraphic components after Hibbard et al. (2006). Abbreviations: EHSZ, Eastern Highlands Shear Zone; MB-GR fault, MacIntosh Brook – Georges River fault.

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Figure 2

Figure 2. Geological map of the Creignish Hills – North Mountain area after White and Boehner (2008) and Swanton et al. (2010). Geology in the southwestern part of the Creignish Hills and North Mountain areas is modified from Giles et al. (2010). Approximate locations for dated samples are shown as stars. Black star indicates location of a sample that yielded no zircon grains, as described in text.

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GEOLOGICAL SETTING

The Bras d’Or terrane of central Cape Breton Island is characterized by low- to high-grade metamorphic rocks intruded by abundant plutons of mainly Late Neoproterozoic age (Fig. 1). Barr and Raeside (1989) and Raeside and Barr (1990) documented tectonostratigraphic differences between these characteristic components of the Bras d’Or terrane and rocks of similar age that characterize the Avalonian Mira terrane of southeastern Cape Breton Island. Those differences have been supported by a number of subsequent studies (e.g., Barr et al. 1995, 1998; Potter et al. 2008a, b), and led to the inclusion of the Bras d’Or terrane, along with similar areas in central Newfoundland and southern New Brunswick, in Ganderia by Hibbard et al. (2006). In contrast, a number of other studies have focused on age similarities between rock units in the Bras d’Or and Mira terranes, and have produced alternative models based on the interpretation that these areas were not separate in the Neoproterozoic (e.g., Keppie and Dostal 1998; Keppie et al. 1990, 1998a, 2000).

The boundary between the Bras d’Or and Mira terranes of Barr and Raeside (1989) is placed in Bras d’Or Lake between North Mountain and Sporting Mountain (Fig. 1). It extends to the northeast through the Boisdale Hills where it coincides with a Carboniferous fault system (MacIntosh Brook – Georges River). From there it has been postulated to extend across the Cabot Strait to the south coast of Newfoundland (Barr et al. 1998, 2014a; Rogers et al. 2006). To the southwest, the terrane boundary is suggested to be offset at the Strait of Canso by the Canso fault and inferred to follow the western margin of the Creignish Hills (King 2002; Barr et al. 2012).

The northern boundary of the Bras d’Or terrane is assumed to be located north of the Creignish Hills beneath Carboniferous rocks. This interpretation is based on the occurrence southwest of Lake Ainslie of rhyolite and granite similar to those in the Lake Ainslie-Gillanders Mountain area of the Aspy terrane (Barr and Jamieson 1991). To the northeast, the boundary is inferred to follow high-strain zones through the central Cape Breton Highlands (Fig. 1). However, the relationship between the Bras d’Or and Aspy terranes is uncertain; available evidence suggests that they are linked in a complex basement/cover relationship, and that Bras d’Or terrane “basement” is likely present under Aspy terrane (e.g., Lin 1993, 1995, 2001; Lin et al. 2007; Price et al. 1999).

Traditionally, most metamorphic rocks in the Bras d’Or terrane were termed the George River Series or Group (e.g., Milligan 1970; Keppie 1979). Raeside and Barr (1990) subdivided these rocks into two assemblages based on metamorphic grade: mainly lower grade units collectively termed the George River metamorphic suite and mainly higher grade and typically gneissic units termed the Bras d’Or metamorphic suite. They also proposed local names for components of both of these metamorphic suites in different areas of the terrane because correlations among them could not be verified. Keppie (2000) termed the higher grade units the Bras d’Or Gneiss, rather than metamorphic suite, but the latter term is retained here as not all components of the unit are gneissic. Rocks of the George River and Bras d’Or metamorphic suites are everywhere separated from one another by known or inferred faults, or by plutonic units, and hence their relationship is enigmatic. Similarities in rock types suggest that they are the same rocks with different metamorphic histories (e.g., Barr et al. 2013) but even if so, their distribution and geological relations are difficult to explain, as exemplified by the map patterns in Figures 1 and 2.

GEORGE RIVER METAMORPHIC SUITE IN THE CREIGNISH HILLS – NORTH MOUNTAIN AREAS

The lower grade (mainly greenschist facies) metamorphic rocks in the Creignish Hills have been named the Blues Brook Formation (Raeside and Barr 1990; Campbell 1990). A compilation of previous work combined with their own mapping led White and Boehner (2008) to divide the Blues Brook Formation into 5 unnamed members, based on dominant rock types (Fig. 2): (1) slate interbedded with minor metasandstone, metasiltstone, and metacarbonate rocks (member sl); (2) metacarbonate rock interbedded with minor metasandstone, metasiltstone, slate, and quartzite (member ca); (3) mainly quartzite interbedded with minor metacarbonate rocks (member qz); (4) a volcanic unit consisting mainly of metamorphosed andesitic to basaltic lithic and lithic crystal tuff with minor basalt flows (member vt); and (5) metasandstone and metasiltstone interbedded with minor slate, metacarbonate rocks, quartzite, and rare basaltic lithic tuff (member ss). Similarities in rock types and their map distribution suggest that the members were originally a single stratigraphic succession, although younging directions are poorly preserved and lateral equivalency is possible.

In the extension of the Creignish Hills into the Lewis Mountain – Aberdeen Ridge area to the northeast, Swanton (2010) and Swanton et al. (2010) also recognized the Blues Brook Formation, including a small area of massive white quartzite (member qz; Fig. 2). However, the remaining rocks in the formation in that area could not be readily assigned to any of the other members of White and Boehner (2008) and hence two additional members were identified: member ps, mainly pelitic schist interbedded with subordinate metacarbonate rocks, amphibolite, and quartzite and member qf, quartzofeldspathic schist with quartzite, metaconglomerate, and minor amphibolite (Fig. 2). To the east along the shore of Bras d’Or Lake, Swanton et al. (2010) identified a separate formation, Aberdeen Ridge, which consists of muscovite-chlorite quartzite with minor amphibolite.

In the North Mountain area to the south (Figs. 1, 2), the lower grade metamorphic rocks have been named the Malagawatch Formation (Raeside and Barr 1990; Justino 1991). The Malagawatch Formation has not yet been subdivided into members but consists of an assemblage of rock types similar to those of the Blues Brook Formation, including metasiltstone, slate, calcitic and dolomitic marble, calc-silicate rocks, minor quartzite, and mafic metavolcanic rocks (Justino 1991).

Rocks of the Blues Brook Formation are regionally metamorphosed to greenschist facies and grade into lower amphibolite facies in the Whycocomagh Mountain area (Armitage 1989; Campbell 1990; Swanton 2010; Swanton et al. (2010). The metamorphic mineral assemblage in most of the pelitic rocks consists of chlorite, muscovite, biotite, and albitic plagioclase whereas in the Whycocomagh Mountain area the grade is higher and garnet and andalusite are present. Most of the metacarbonate rocks are monomineralic (calcite or dolomite) but locally contain talc, muscovite, phlogopite, garnet, and minor tremolite. In the higher metamorphic grade calc-silicate rocks diopside and forsterite are present (Armitage 1989). The mafic metavolcanic rocks have been metamorphosed to assemblages of actinolite, chlorite, and albitic plagioclase; stilpnomelane has also been reported (Campbell 1990). Contact metamorphic effects are locally well developed around some of the plutonic units and most evident in the pelitic rocks where a hornfelsic texture is preserved containing randomly oriented biotite, cordierite, and rare andalusite.

The protolith age of these metamorphic units is constrained to greater than ca. 586 Ma by dating of mainly undeformed cross-cutting plutons, as described below. However, they have generally been assumed to be much older than 586 Ma, perhaps Mesoproterozoic, based on the presence of stromatolite-like structures in the Malagawatch Formation, similar to those in the Green Head Group of southern New Brunswick which are of inferred Early Proterozoic age (Hofmann 1974; White and Barr 1996; White et al. 2007). This interpretation has been supported by detrital zircon populations that are mainly Archean and Mesoproterozoic in quartzite samples from both areas (Keppie et al. 1998a; Barr et al. 2003). However, a sample of schist from the Blues Brook Formation (Fig. 2) yielded 2 euhedral zircon grains with slightly discordant 206Pb/238U ages of 637 ± 3 Ma and 638 ± 2 Ma (Keppie et al. 1998a). Keppie et al.(1998a) interpreted the schist to have formed from a felsic volcanogenic unit, and the ages to be the age of the igneous protolith. If so, these dates are a maximum age for the Blues Brook Formation and, by inference, other units in the George River metamorphic suite. A younger 40Ar/39Ar cooling age of 455 ± 1 Ma was reported for muscovite from the same area (Keppie et al. 2000). Campbell (1990) obtained older muscovite ages of ca. 625 Ma from elsewhere in the same unit, but those data are unpublished and of uncertain reliability.

BRAS D’OR METAMORPHIC SUITE IN THE CREIGNISH HILLS – NORTH MOUNTAIN AREAS

Keppie (1993), Keppie et al. (1998a), and Wessel et al. (2005) interpreted the presence of a folded shear zone between the low- and high-grade rocks in the Skye Mountain area of the Creignish Hills. They postulated that this shear zone repeatedly intersects the present erosion surface, implying that it is a low-angle tectonic boundary in which the high-grade rocks occur in structural domes. That interpretation was not adopted by White and Boehner (2008), who divided the high-grade metamorphic rocks in the Creignish Hills into two units, one at the northeastern tip for which they used the name Skye Mountain metamorphic suite, and the other, which they termed the Melford Formation, in two areas to the southwest: a fault-bounded block across the trend of the Creignish Hills in the northeast, and a smaller area near Melford in the central part of the Creignish Hills (Fig. 2). This distinction was made because the rocks in the latter two areas are not generally gneissic and differ in rock types from those in the area at the northeastern tip. We here introduce the name Chuggin Road instead of Skye Mountain for the rocks at the northeastern tip of the Creignish Hills because that area is not geographically located on Skye Mountain, and furthermore, the name Skye Mountain has long been used for plutonic rocks in the Skye Mountain area (see below). The area of high-grade rocks shown by Armitage (1989), Raeside and Barr (1990), and White and Boehner (2008) on Whycocomagh Mountain was reassigned by Swanton (2010) and Swanton et al. (2010) to the Blues Brook Formation as noted above, based on rock types and metamorphic grade. In the North Mountain area, rocks of the Bras d’Or metamorphic suite are known as the Lime Hill gneissic complex and occur in a large area in the south-central part of North Mountain (Fig. 2).

As described by Raeside (1990), Raeside and Barr (1990), Campbell (1990), and Sangster et al. (1990) the high-grade metamorphic rocks in both the Chuggin Road and Lime Hill units include biotite, bioitite-cordierite, and sillimanite-bearing paragneiss, migmatitic paragneiss, marble, quartzite, amphibolite, and tonalitic orthogneiss. In contrast, the Melford Formation has somewhat different rock types, including biotite, biotite-cordierite, sillimanite, and garnet-bearing schist, marble, quartzite, and granitic orthogneiss (White and Boehner 2008).

Keppie et al. (1998a) provided age constraints on rocks in the Melford Formation of White and Boehner (2008). A muscovite-biotite ‘paragneiss’ from the southern block yielded mainly mid-Proterozoic ages, but the youngest grain is ca. 977 Ma (Keppie et al. 1998a). A pelitic paragneiss inferred to have a volcanogenic protolith in the fault-bounded block at Skye Mountain yielded zircon grains with 206Pb/238U ages between 688 Ma and 694 Ma (Keppie et al. 1998a). These ages were interpreted to be the best estimate of igneous crystallization ages for the inferred volcanogenic protolith. A monazite grain interpreted to be of metamorphic origin in the same sample yielded a concordant age of 552 ± 8 Ma. Farther north and also in the Melford Formation of White and Boehner (2008), a foliated granitic sheet, considered to be syntectonic, yielded two concordant monazite grains with ages of 551±1 Ma, interpreted to be igneous crystallization ages (Keppie et al. 1998a). Two zircon grains yielded discordant but similar ages of ca. 553 Ma. These ages provide a minimum age for the Melford Formation. In contrast to these Precambrian ages, 40Ar/39Ar ages from muscovite in the Melford Formation are younger: 441, 449, 461, 473, and 485 Ma (Campbell 1990; Dallmeyer and Keppie 1993; Keppie et al. 1998a). Similar 40Ar/39Ar ages were reported for muscovite (484, 524 Ma) and biotite (485 Ma) from the area of Melford Formation to the south near Melford (Campbell 1990; Keppie et al. 2000) and muscovite from the Melford pluton (Keppie et al. 2000). An igneous crystallization age of ca. 561 Ma reported by White et al. (2003) for orthogneiss in the Chuggin Road metamorphic suite is described below.

In the case of the Lime Hill gneissic complex, ages are constrained by a concordant U-Pb monazite date from paragneiss at 549±2 Ma, and syn- and post-tectonic plutons that yielded discordant U-Pb (zircon) data with lower intercepts of 539 ± 1 Ma and 545–540 Ma (Sangster et al. 1990). An additional constraint is provided by a concordant monazite age of 553 ± 1 Ma from an anatectic granite sheet in pelitic paragneiss, interpreted to represent the time of peak metamorphism (Keppie et al. 1998a). Keppie et al. (1998a) reported that another monazite grain and rounded zircon grains from the same sheet yielded older but discordant ages.

PLUTONIC ROCKS

Dioritic to granitic plutons intruded both the low- and high-grade metamorphic units in both the Creignish Hills and North Mountain areas (Fig. 2). White et al. (1990) assigned most of the plutonic rocks in the Creignish Hills area to the Creignish Hills pluton, and subdivided the pluton into five units based on modal mineralogy; texture, and lithogeochemistry: tonalite-diorite, granodiorite-tonalite, granodiorite-monzogranite, coarse-grained monzogranite, and fine-grained monzogranite. This work was done in the early days of geochronological work in Cape Breton Island, and the authors were much influenced by an Rb-Sr isochron using a range of rock types which indicated an age of about 446 Ma. However, 40Ar/39Ar cooling ages of ca. 540 Ma from hornblende in the tonalite – diorite unit indicated a much older minimum age for that body. Furthermore, the granitic components of the pluton had petrological similarities to the Kellys Mountain and Cape Smokey plutons which had yielded U-Pb (zircon) ages of 498 and 493 Ma, respectively. Overall, it was concluded based on the available data that the rocks are (questionably) of Ordovician age. Two small plutons in the northeastern part of the belt were together named the Skye Mountain pluton, described as separate bodies of gabbro and granodiorite, and assigned an age anywhere between Precambrian and Carboniferous (White et al. 1990). These plutons were reported to differ from any of the components of the Creignish Hills pluton based on descriptions provided by earlier workers but were not part of the study by White et al. (1990).

Knowledge of the ages of these plutons was much improved as a result of work by Keppie et al. (2000), who reported U-Pb (zircon) ages of 553 ± 2 for a sample from the largest tonalite-diorite body of the Creignish Hills pluton. This age is consistent with the previously reported ca. 544 Ma hornblende cooling age from that body (Keppie et al. 1990). However, a smaller body of tonalite (River Denys pluton of Keppie et al. 2000) yielded a younger U-Pb age of 540±3 Ma, although 40Ar/39Ar ages for amphibole from the same sample and another sample in the same unit are older (ca. 550 and 551 Ma; Keppie et al. 1990). Keppie et al. (2000) concluded that, overall, these 540–550 Ma ages “post-date closely the time of intrusion”, and that the River Denys Pluton is part of the same magmatic event as the 553 Ma diorite of the Creignish Hills pluton. The age of the Creignish Hills pluton was further constrained by a ca. 553 Ma age for the main granitic unit reported by White et al. (2003) and presented below.

In contrast to these Neoproterozoic ages, a sample reported to be from the gabbro-diorite body of the Skye Mountain pluton yielded a Silurian age of 438 ± 2 Ma (Keppie et al. 1998b, 2000). A sample from the separate granitic body to the west yielded only old (ca. 737 Ma) discordant zircon grains, but Keppie et al. (2000) inferred a Silurian age, based on muscovite plateau ages in the surrounding host rocks, especially an age of 441 Ma from what they interpreted to be the contact metamorphic aureole adjacent to the granite. Keppie et al. (2000) and Wessel et al. (2005) showed the Skye Mountain granite and gabbro-diorite as contiguous bodies on their maps, whereas previous maps (White et al. 1990; Horton 1994) showed them as separate bodies. Horton (1994) interpreted them to be unrelated based on their very different petrographic and chemical characteristics. He considered the foliated granitic sheet in the Melford Formation north of the pluton to be related to the granite and hence its ca. 551 Ma age to be the age of the pluton.

After a re-evaluation of outcrop locations and additional mapping in the area, White and Boenher (2008) confirmed that the two plutons are separated by a belt of rocks of the Melford Formation. They included the western (granitic) pluton in the Creignish Hills pluton, to which it is petrographically similar, and inferred a similar ca. 550 Ma age. Hence, to avoid further confusion, the name Skye Mountain is retained here for only the gabbroic-dioritic body and a new name, Skye Mountain Road, is introduced for the western body, named after the road on which it is best exposed.

The small granitic body termed the Melford pluton by Keppie et al. (2000) yielded an older U-Pb (zircon) age of 586 ± 2 Ma, although this two-point upper intercept age is of limited reliability. The pluton intruded gneissic rocks assigned by Keppie et al. (2000) to the Bras d’Or Gneiss (Melford Formation in this study), and was interpreted to be late syn-tectonic based on the presence of a weak foliation parallel to that in its host rocks. White and Boehner (2008) showed that the pluton is larger than suggested by Keppie et al. (2000), and that it is faulted on its southwestern and northwestern edges against rocks of the Blues Brook Formation. They included the pluton in the granitic unit of the Creignish Hills pluton, in spite of its apparently somewhat older age and the occurrence of muscovite for which Keppie et al. (2000) reported a cooling age of 472 Ma. Muscovite is not a typical component of the Creignish Hills granite but has also been reported in part of the Skye Mountain Road pluton (Horton 1994).

Plutons form most of the North Mountain area, and were studied in detail by Justino (1991) and Justino and Barr (1994). Those authors divided the plutonic rocks into the Big Brook and Marble Mountain plutons, of mainly granodiorite composition, and the West Bay Pluton, composed of coarse-grained monzogranite. The latter pluton is cut off by a fault according to the map by Giles et al. (2010) but likely extends south of the fault with minor offset, based on the presence of outcrops of similar granite in the Sugar Camp gypsum quarry (Fig. 2). Small tonalitic to dioritic bodies (Mill Brook quartz diorite and related plutons) occur along the margins of these large plutons. Age constraints are provided by 40Ar/39Ar hornblende cooling ages of 555 ± 5 Ma apparently from the Marble Mountain biotite granodiorite unit (based on approximate location shown by Keppie et al. 1990) and 550 ± 5 Ma and 545 ± 6 Ma on two separate bodies of the Mill Brook quartz diorite (Keppie et al. 1990) and the ca. 553 Ma age for the West Bay Granite reported by White et al. (2003) and presented below.

GEOCHRONOLOGY

Methods

In this paper we report new detrital zircon ages for a sample (SMB14-189A) collected from the same location as sample 11Z reported by Keppie et al. (1998a). We resampled this site in order to further investigate the hints of young zircon grains in sample 11Z. The methods and data table are presented in Appendix A. We also resampled at the same location in the Melford Formation as paragneiss sample 188Z of Keppie et al. (1998a) but the sample yielded no zircon grains suitable for analysis.

We also present the data for the ages published in preliminary form by White et al. (2003). The methods and data tables are presented in Appendix B.

Muscovite was separated from a sample of mica schist interlayered with marble in unit ss near the southern margin of the Creignish Hills (Fig. 2). The analytical method and data are presented in Appendix C (Table C1).

Results

Sample SMB14-189A

Sample SMB14-189A from the Blues Brook Formation (UTM coordinates 5090806N, 637216E) yielded a small amount of tiny rounded zircon grains. Clear areas on the zircon grains were targeted for analysis so as to avoid cracks. U-Pb analyses are all near- concordant (Appendix Table A1) and give a wide range of Neoproterozoic to Archean ages (Fig. 3a). A subset of brownish grains proved to be relatively old, and included the two Archean grains (Table A1). Over half of the grains are grouped into a relatively tight cluster with 206Pb/238U ages that vary over the range of about 600–700 Ma (Fig. 3a). Deposition of the unit was therefore at or younger than 600 Ma and much of the detritus in the sample was derived from Neoproterozoic rocks.

Figure 3

Figure 3. (a) U-Pb concordia diagram and probability plot constructed using Isoplot (Ludwig 2003) for sample SMB14-189A. (b) Comparision between the probability plot from (a) and that for the Martinon Formation in the Brookville terrane of southern New Brunswick from Barr et al. (2014b). Methods are described in Appendix A and data are in Table A1.

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Sample SMB02-81

Sample SMB02-81, collected from an active quarry near Chuggin Road northwest of Whycocomagh (UTM coordinates 5094125N, 642350E), is a fine- to medium-grained tonalitic orthogneiss that consists mostly of quartz, plagioclase, and biotite. It is interpreted as an orthogneiss based on its homogeneous appearance in outcrop and on the presence of relict weakly zoned plagioclase grains visible in thin section. A relatively high Th/U ratio (mostly >0.5) in the zircon is also consistent with an igneous origin. The zircon population obtained from the sample is characterized by colourless, good-quality euhedral and subhedral prisms ranging from equant to elongate with length to breadth ratio of 3:1 to 4:1. Many equant grains are distinctly zoned with an apparent euhedral overgrowth component, but this component is not present on most long prisms. Four fractions consisting of long prisms (length:breadth >3:1), both with and without tiny fluid inclusions, are concordant or near-concordant at 565–560 Ma (Fig. 4a; Table B1). Their average 207Pb/206Pb age of 561 ± 3 Ma is interpreted as the igneous crystallization age of the tonalite, although we acknowledge that a slightly older age of ca. 565 ± 3 Ma (based on the 206Pb/238U age of analysis Z1) is possible. Two additional fractions (1 and 4 grains each) of equant, colourless grains give discordant results indicating mid-Proterozoic inheritance (Fig. 4a). The age constrains the age of metasedimentary components of the Chuggin Road and other parts of the Bras d’Or metamorphic suite to greater than ca. 565 Ma.

Figure 4

Figure 4. U-Pb Concordia diagrams for metaigneous and igneous samples. Methods are described in Appendix B and data are in Table B1.

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Sample SMB02-79

The Creignish Hills pluton was sampled for dating on a logging road in the south-central part of the Creignish Hills (UTM coordinates 5071750N, 626375E). Sample SMB02-79 is typical of the medium- to coarse-grained monzogranitic unit that forms most of the pluton (White et al. 1990). It consists of quartz, K-feldspar (perthitic orthoclase), and plagioclase in approximately equal proportions, with minor biotite and hornblende. It yielded abundant equant to 2:1, euhedral, four-sided zircon prisms of varying size. Fluid inclusions are relatively common and opaque mineral inclusions were also observed. Four concordant or near-concordant single grain and multigrain fractions (Table B1) have an average 207Pb/206Pb age of 553 +/- 3 Ma (Fig. 4b) which we interpret as the crystallization age of the granite.

Sample SMB02-83

The West Bay Granite was sampled in a quarry at the southwestern margin of North Mountain (UTM coordinates 5066850N, 641000E). The dated sample is coarse-grained monzogranite, with K-feldspar megacrysts up to 5 cm in length. Mafic minerals (biotite and possibly hornblende) have been replaced by chlorite. The zircon population in this sample appears identical to that for sample SMB02-79, and three near-concordant single grain and 2-grain fractions (Table B1) yield an identical crystallization age of 553 ± 2 Ma (Fig. 4c).

Sample SMB06-111

Muscovite schist sample SMB06-111 was collected from a small quarry in the Blues Brook Formation near the faulted southeastern margin of the Creignish Hills (Fig. 2). To reduce the possibility of homogenization of Ar isotopes during traditional incremental heating of muscovite and to reduce any core-rim effect (i.e., intracrystalline age discordance), standard single-grain, laser fusion 40Ar/39Ar ages were used (e.g., Hames et al. 2008). Hence, each analysis is a mean age of the muscovite grain (Appendix C). Total fusion analyses of 23 single muscovite grains yielded apparent ages ranging from 488 Ma to 430 Ma (Table C1). Displayed on a histogram (Fig. 5), ages cover the range between those high- and low-age cutoffs. The simplest interpretation is that these ages represent partial resetting of older (>500 Ma) muscovite at about 430 Ma (see further discussion below). Because the dated sample is from near the major faulted margin of the Creignish Hills, it is likely that the resetting is a result of deformation (e.g., Mulch and Cosca 2004).

Figure 5

Figure 5. Histogram for single-grain white mica 40Ar/39Ar total-fusion analyses from sample SMB06-111. Methods are described in Appendix C and data are in Table C1.

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DISCUSSION

Age of the George River and Bras d’Or metamorphic suites

Keppie and Dostal (1998) interpreted that the George River metamorphic suite (Blues Brook and Malagawatch formations) in the Creignish Hills and North Mountain areas consists of two parts – an older non-volcanogenic sedimentary package (quartzite, marble, schist, phyllite) and a younger volcanogenic package in which similar rocks are interlayered with felsic volcanogenic rocks and mafic flows. Based on their U-Pb data (summarized above), they estimated depositional ages of ~977–700 Ma and ~694–637 Ma, respectively, for these two packages. They showed that the mafic volcanic rocks in the inferred younger package are within-plate tholeiite, and attributed them to a back-arc basin associated with a volcanic arc of similar age in the Stirling belt of the now-adjacent Avalonian Mira terrane. Our sample from the same location as the sample that yielded the ~694 and 637 Ma ages contains abundant grains as young as 600 Ma, showing that the maximum depositional age for the unit is younger than suggested by the data of Keppie et al. (1998a). These new data are inconsistent with the interpretation made by Keppie and Dostal (1998) that the rocks formed in a back-arc related to the birth of arc magmatism in Avalonia because the main pulse of arc magmatism in many parts of Avalonia, including the now-adjacent Mira terrane, is at about 620 Ma and arc-related rocks as old as 680 Ma are documented in the Mira terrane (Barr et al. 1996, 1998). These rocks are clearly older than the depositional age of at least part of the Blues Brook and Malagawatch formations. It also makes the chemical characteristics documented by Keppie and Dostal (1998) difficult to interpret, as discussed further in the next section.

Based on field relations and similarities in rock types, it seems unlikely that the components of the Blues Brook and Malagawatch formations are of widely different ages. White and Boehner (2008) interpreted the units to form a single stratigraphic succession. The minimum age is constrained by the abundant plutons with ages of ca. 550 Ma that intruded these rocks. Hence it seems that these sediments were deposited, regionally metamorphosed and deformed, and intruded by abundant plutons in less than 50 million years.

Only sparse detrital zircon data are available from other metasedimentary rocks in the Creignish Hills and Bras d’Or terrane in general (Keppie et al. 1998a; Barr et al. 2003), but a larger database is available from the Brookville terrane of southern New Brunswick. The detrital zircon age signature displayed by sample SMB14-189A is similar, especially in its Late Mesozoic to Neoproterozoic to part, to that of the Martinon Formation in New Brunswick, in which the most abundant zircon grains have ages between 650 and 600 Ma, and many fewer grains have ages between 1000 Ma and 2200 Ma (Fig. 3b). Like the Blues Brook Formation, the Martinon Formation is part of the low-grade metasedimentary assemblage in the Brookville terrane, and closely associated with quartzite and marble, which locally contains stromatolite-like structures. Similarity in detrital zircon signatures between the >1000 Ma grains in the associated quartzite as well as in the high-grade assemblage (Brookville Gneiss) in the terrane led Barr et al. (2014b) to conclude that the high- and low-grade rocks are related, although the quartzite and paragneiss age spectra lack the 650–600 Ma zircon grains. Based on the results of Keppie et al. (1998a), the same situation exists in the Creignish Hills, although one sample of paragneiss from the Melford Formation contains grains as young as 688 Ma and 694 Ma (Keppie et al. 1998a). Resampling at that locality for the present study (black star, Fig. 2) did not result in any zircon grains which could have better constrained those younger ages.

The age of ca. 561 Ma from orthogneiss in the Chuggin Road complex (Fig. 4a) provides a minimum age for the Bras d’Or metamorphic suite and a maximum age for regional metamorphism. It is supported by several monazite and zircon ages of ca. 550 Ma reported by Keppie et al. (1998a) and Sangster et al. (1990) from the Creignish Hills and North Mountain areas (Figs. 6a, b). All of these data indicate a major thermal event at that time, coincident with regional metamorphism and widespread magmatic activity as discussed further in the subsequent section.

The assemblage of pelitic, psammitic, and carbonate rocks in the Blues Brook and Malagawatch formations and the likely correlative high-grade units indicates that they formed on a passive margin in a tropical climate, as also inferred for the Brookville terrane in southern New Brunswick (Barr et al. 2014b). Barr et al. (2014b) suggested that this passive margin was located on the Proto-Andean - Caribbean edge of Amazonia after it had separated from Laurentia by ca. 650 Ma.

Figure 6

Figure 6. Histograms summarizing (a) U-Pb zircon and U-Pb monazite ages interpreted as igneous crystallization ages for plutonic units in the Creignish Hills and North Mountain areas and (b) 40Ar/39Ar muscovite and hornblende ages from igneous and metamorphic units and U-Pb (monazite) ages interpreted to be metamorphic ages as described in the text. U-Pb (zircon) igneous crystallization ages from other plutonic units in the Bras d’Or terrane (Cape Smokey granite, Kellys Mountain granite, Cameron Mountain syenogranite, Ingonish River tonalite, Gisborne Flowage quartz diorite, Birch Plain granite, Indian Brook granodiorite, Kathy Road diorite, Baddeck River granodiorite, Shunacadie granite, and Boisdale Hills tonalite dyke) are shown for comparison. Data sources are referenced in the text.

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Pluton ages and geochemistry

The U-Pb igneous crystallization ages from zircon and monazite in plutonic rocks ranging from dioritic to granitic in the Creignish Hills and North Mountain areas cluster at about 550 Ma (Fig. 6a). The fact that 40Ar/39Ar cooling ages from amphibole in these units are similar to the zircon ages (Figs. 6a, b) indicates that these plutons cooled quickly and hence were probably epizonal, as also noted by Keppie et al. (1990) and Dallmeyer and Keppie (1993). In contrast to previous suggestions based on less reliable age estimates (White et al. 1990; Raeside and Barr 1990), the granitic rocks are the same age as the dioritic and tonalitic rocks and did not form in a separate, much younger igneous event.

This interpretation is further supported by chemical characteristics which show coherence among all of the known and inferred Neoproterozoic plutons in the Creignish Hills and North Mountain areas, as illustrated in Figure 7. With the exception of 3 new analyses (Table D1), the chemical data depicted on this figure have been previously published in theses and papers. Hence we are not presenting the data again but include instead a list of sample numbers and data sources (Table D2), as the analyses may not have been identified with the correct age or pluton in the original paper.

Figure 7

Figure 7. Plots of (a) TiO2, (b) Al2O3, (c) Fe2O3T, and (d) CaO against SiO2 and (e) normative mineralogy to illustrate chemical variation in the ca. 560–550 Ma plutonic rocks of the Creignish Hills - North Mountain areas. Data are from Table D1 and sources cited in Table D2. Fields in (e) are from Streckeisen and LeMaitre (1979).

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As illustrated in Figure 7, the analyses from the Skye Mountain Road pluton (data from Horton 1994) are similar to those from the other granitic and granodioritic plutons, consistent with the interpretation that it is the same ca. 550 Ma age and not Silurian like the Skye Mountain diorite-gabbro. Similarly, the River Denys tonalite is chemically similar to other dioritic and tonalitic components of the Creignish Hills pluton, consistent with the interpretation of Keppie et al. (1998a) that the plutonic rocks are part of a single magmatic episode, even though ages show some variation. No chemical data are available from the possibly older (ca. 586 Ma) Melford pluton to indicate whether or not it is chemically similar to the other plutons, but White and Boehner (2008) correlated it with the coarse-grained granitic unit of the Creignish Hills pluton based on petrographic features.

With an igneous crystallization age of ca. 561 Ma, the tonalitic orthogneiss in the Chuggin Road metamorphic suite is also slightly older than the dominant ca. 550 Ma plutons of the Creignish Hills – North Mountain area, but dioritic, tonalitic, and granodioritic plutons elsewhere in the Bras d’Or terrane have yielded U-Pb (zircon) crystallization ages as old as 565 Ma (Fig. 6a). The Chuggin Road orthogneiss sample has chemical characteristics that are generally similar to other plutonic samples with similar silica content, but it has higher CaO and hence plots somewhat separately in terms of normative mineralogy (Fig. 7e).

Overall, samples from all of the plutons show the range of compositions typical of I-type granitoid suites (Fig. 7). They lie on a calc-alkalic trend on an AFM diagram (Fig. 8a), and range from metaluminous in the more mafic samples to peraluminous in the felsic samples (Fig. 8b). They have trace element characteristics of volcanic-arc granites, evolving toward within-plate characteristics in the most felsic (evolved) samples (Fig. 8c). These characteristics are shared by Neoproterozoic plutons throughout the Bras d’Or terrane (e.g., Farrow and Barr 1992; Raeside and Barr 1990; Grecco and Barr 1999; Wasylik et al. 2005; Swanton 2010). It is clear that a huge volume of plutonic rocks was emplaced in the Bras d’Or terrane mainly between about 565–550 Ma and that they formed in an Andeantype continental margin subduction zone. A similar interpretation has been made for the Brookville terrane of southern New Brunswick, although the pluton ages there are overall younger at 550–525 Ma (White et al. 2002).

Figure 8

Figure 8. Diagrams to illustrate chemical affinity and tectonic setting for ca. 560–550 Ma plutonic rocks of the Creignish Hills - North Mountain areas. (a) AFM diagram with tholeiitic-calc-alkalic dividing line after Irvine and Baragar (1971). (b) Plot of molecular proportions of Al2O3/(Na2O+K2O) against Al2O3/(CaO+Na2O+K2O). (c) Tectonic setting discrimination diagram with fields from Pearce et al. (1984). Symbols are as in Figure 7.

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Significance of muscovite ages

As noted above, 40Ar/39Ar cooling ages from muscovite in both plutonic and metamorphic rocks of the Creignish Hills are younger than most of the pluton crystallization ages, whereas the hornblende ages reflect pluton cooling at ca. 550–540 Ma (Figs. 6a, b). Examining the geographic distribution of the muscovite ages reported by Dallmeyer and Keppie (1993) from the Creignish Hills, most if not all samples are from proximity to the major shear zones which cross the area. The sample dated in the present study is from near the faulted southeastern margin of the Blues Brook Formation (Fig. 2). The age data shown in Figure 5 are statistically too few to attach significance to the internal peaks, but if the upper and lower bounds of the data have significance, they suggest that muscovite with a minimum age of 500 Ma was variably reset at about 430 Ma. The other age data (U-Pb zircon and monazite and 40Ar/39Ar amphibole) suggest that the likely initial age of the muscovite is ca. 550 Ma, the approximate time of regional metamorphism and pluton emplacement in the Bras d’Or terrane. Scattered plutons elsewhere in the Bras d’Or terrane with ages of ca. 500 Ma are post-tectonic, and little other evidence exists for a ca. 500 Ma thermal event in the Bras d’Or terrane (Figs. 6a, b). The variable resetting of the muscovite ages could have been related to the emplacement of the Skye Mountain dioritegabbro at ca. 438 Ma, but given that the young muscovite ages occur widely through the Creignish Hills (Dallmeyer and Keppie 1993), it seems more likely that the resetting was related to deformation in the major shear zones in the area (Fig. 2). More detailed 40Ar/39Ar work throughout the Bras d’Or terrane is needed in order to interpret the Paleozoic thermal history as recorded in these muscovite ages.

CONCLUSIONS

The U-Pb ages presented here for detrital zircon in the Blues Brook Formation of the Creignish Hills confirm the hints of Late Neoproterozoic ages reported by Keppie et al. (1998a) and show without doubt that the depositional age of the unit is no greater than about 600 Ma. Although it is possible that some components of the formation are much older, such as the quartzite in which the youngest detrital zircon age obtained is ca. 1000 Ma (Keppie et al. 1998a), similarities in rock types and contiguous field relations suggest that this is not the case. Based on similarities in rock types and previously published detrital zircon ages of ca. 690 Ma (Keppie et al. 1998a), it is likely that the high-grade metasedimentary rocks of the Melford Formation and Chuggin Road complex are of the same age, and that they represent the same or stratigraphically equivalent units at higher metamorphic grade, rather than unrelated units. The minimum ages of both the low- and high-grade units in the Creignish Hills and nearby North Mountain are provided by cross-cutting syn- and post-tectonic plutons with ages of mainly 565–550 Ma, indicating that sediments were deposited, regionally metamorphosed and deformed, and intruded by plutons in less than 40–50 million years. The assemblage of pelitic, psammitic, and carbonate rocks indicates that a passive margin in a tropical climate was quickly changed to an active Andean-type continental margin in which voluminous calc-alkaline dioritic to granitic plutons were emplaced. This sedimentary and tectonic history is characteristic of the Bras d’Or terrane and is shared by its likely correlative, the Brookville terrane in southern New Brunswick (Barr et al. 2014b).